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The fastest is through the lungs, and a bit slower by the mucosa of the nose and mouth

Pulmonary Exposure to Diesel Exhaust Particles Promotes Cerebral Microvessel Thrombosis: Protective Effect of a Cysteine Prodrug L-2-Oxothiazolidine-4-Carboxylic Acid

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And as you likely already realize, this is just one piece of the puzzle in how this habit is destroying you from the inside out